====== Paper: Long-Range Hydrophobic Attraction Between Graphene and Water/Oil Interfaces ======

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| //**Authors from our Lab:** \_ Avishi Abeywickrama, Douglas H. Adamson, and [[:public:team:schniepp|Hannes C. Schniepp]]// \\ **Published:** Jul. 28, 2023 \_
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**{{ :public:publications:2022_mat_horiz_bhs.png?400&direct|}} Long-range hydrophobic attractions between mesoscopic surfaces in water play an important role in many colloid and interface phenomena. Despite being studied by several approaches, the origin of these forces has yet to be adequately explained. While previous research has focused on solid/water/solid and solid/water/air scenarios, we investigated a solid/water/liquid situation to gain additional insight. We directly measured the long-range interactions between a solid and a hydrophobic liquid separated by water using force spectroscopy, where colloidal probes were coated with graphene oxide (GO) to interact with immobilized heptane droplets in water. We detected attractions with a range of ~0.5 {\mu}m that cannot be explained by standard Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. When the GO was reduced to rGO to become more hydrophobic, these forces increased in strength and ranged up to 1.2 {\mu}m. This suggests that the observed attractions result from long-range hydrophobic forces. Based on our results, we propose air bubbles attached to the colloidal probe and molecular rearrangement at the water/oil interface as possible origins of the observed interactions. This knowledge will be useful to understand and motivate the formation of emulsions using 2D materials and other amphiphilic/hydrophobic particles.**

Our **{{ :public:publications:2022_mat_horiz_bhs.pdf |paper}}** has been published in the journal //[[https://doi.org/10.1039/D2MH00403H|Materials Horizons]]// (2021 impact factor: 15.71).\\
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Here, you can find our public **[[public:news:blog:2021-2024:2022-07_mat_horiz_press_release|Press Release]]** for this article.

==== Citation ====

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Abeywickrama, A., Adamson, D. H., & Schniepp, H. C. \\
"Long-Range Hydrophobic Attraction Between Graphene and Water/Oil Interfaces" \\
//ArXiv. /abs/2307.15658//  
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[[this>_media/:public:publications:2019_bnnt_paper.pdf|{{:public:news:blog:icon_pdf_48.png?nolink}}]]

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|**PDF Download:**
|{{ :public:publications:2019_bnnt_paper.pdf |Download}}

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|**Contact:**
|[[schniepp@wm.edu|schniepp@wm.edu]]
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|**DOI:**
|[[10.48550/arXiv.2307.15658]]
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|**Publisher's Web Page:**
|[[https://doi.org/10.48550/arXiv.2307.15658]]
|}

==== Links ====

  * **[[https://pubs.acs.org/doi/full/10.1021/acs.chemmater.9b01713|Link to scientific paper]]**
  * **[[:public:research:projects:nanocomposites|More about our nanocomposite research]]**
  * **[[:public:publications|All Publications of the Schniepp group]]**